Methanol Ethanol And N-propanol Are Three Common Alcohols

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Methanol Ethanol And N-propanol Are Three Common Alcohols

Methanol, ethanol, and n-propanol are three common alcohols. When 1.00 g of each of these alcohols is burned in air, heat is liberated as shown by the following data: (a) methanol (CH3OH), –22.6 kJ/g; (b) ethanol (C2H5OH), –29.7 kJ/g; (c) n-propanol (C3H7OH), –33.4 kJ/g.

Methanol Ethanol And N-propanol Are Three Common Alcohols: Constant volume calorimetry is used to study reactions where it is difficult to measure emitted or absorbed heat. It is also known as bomb calorimetry because it is often used to measure the combustion temperatures of materials. Combustion converts liquids and solids into gases. Thus, the pressure inside the calorimeter unit increases significantly. This makes it officially a bomb, because the sudden expansion of gases is the basic mechanism of explosive expansion.

Alkanols form a class of organic chemical compounds formally derived from alkanes, as one or more hydrogen atoms have been replaced by one or more hydroxy groups. In this way, alkanols form a group of special alcohols R-OH together with a saturated hydrocarbon radical R=alkyl radical, which may be branched or unbranched.

Alkanols with several functional OH groups are referred to as alkanediols (2), alkanetriols (3), etc.

Methanol Ethanol And N-propanol Are Three Common Alcohols: The nomenclature of alkanols is based systematically on the name of the respective alkane, to which the syllable -ol is appended (ethane – ethanol). Older names use the alkyl radical as the root name, extended by -‘alcohol’ (ethanol = ethyl alcohol). Trivial names are also common for some alkanes (e.g. lauryl alcohol = 1-dodecanol). The naming of the diols and the triplets (ethane – ethanediol) is analogous.

Properties of n-alkanols

Methanol Ethanol And N-propanol Are Three Common Alcohols: The table below shows some properties of the unbranched (primary) alkyl alcohols or n-alkanols:

Methanol Ethanol And N-propanol Are Three Common Alcohols: Surnamecommon nameformulamolar massmelting pointboiling pointDensity [20 °C]CAS No.
methanolmethyl alcoholCH4O _ _32.04 g mol -1– 97.8ºC64.7°C0.79 g/ml67-56-1
ethanolethyl alcoholC2H6O _ _ _ _46.07 gmol -1– 114.1ºC78.32°C0.7893 g/mL64-17-5
propanoln-propyl alcoholC3H8O _ _ _ _60.10 g mol -1– 126ºC97ºC0.80g/ml71-23-8
butanoln-butyl alcoholC4H10O _ _ _ _74.12 gmol -1– 89ºC118ºC0.81 g/mL71-36-3
pentanolamyl alcoholC5H12O _ _ _ _88.15 g mol -1– 78.9ºC138°C0.8146 g/mL71-41-0
hexanolcaproic alcoholC6H14O _ _ _ _102.18gmol -1– 45ºC157ºC0.823 g/mL111-27-3
heptanolenanthic alcoholC7H16O _ _ _ _116.20 g mol -1– 34ºC175ºC0.82g/mL111-70-6
octanolcaprylic alcoholC8H18O _ _ _ _130.23 g mol -1– 16ºC195ºC0.817 g/mL111-87-5
nonanolpelargonium alcoholC9H20O _ _ _ _140.26 g mol -1– 6ºC450F (214C)0.83 g/ml143-08-8
decanolcapric alcoholC10H22O _ _ _ _158.28 g mol -16.9°C230ºC0.83 g/ml112-30-1
undecanolundecyl alcoholC11H24O _ _ _ _172.31 g mol -119ºC243°C0.83 g/ml112-42-5
dodecanollauryl alcoholC12H26O _ _ _ _186.34 g mol -124°C261°C0.83 g/ml112-53-8
tridecanol C13H28O _ _ _ _200.37 g mol -132°C274°C0.845g/mL112-70-9
tetradecanolmyristyl alcoholC14H30O _ _ _ _214.39 g mol -139ºC289°C0.823 g/mL112-72-1
pentadecanol C15H32O _ _ _ _228.41 g mol -145.4°C0.829 g/mL 629-76-5
hexadecanolcetyl alcohol
palmityl alcohol
C16H34O _ _ _ _242.44 g mol -149°C344°C0.84g/mL36653-82-4
heptadecanolmararyl alcoholC17H36O _ _ _ _256.47 g mol -154°C344°C0.85g/ml1454-85-9
octadecanolstearyl alcoholC18H38O _ _ _ _270.49 g mol -159ºC800F (336C)0.83 g/ml112-92-5
nonadecanol C19H40O _ _ _ _284.52 g mol -163.3°C 3511454-84-8
Eicosanolarachidyl alcoholC20H42O _ _ _ _298.55 g mol -166.1°C800F (372C)0.80g/ml629-96-9
henicosanol C21H44O _ _ _ _312.57 g mol -115594-90-8
docosanolbehenyl alcoholC22H46O _ _ _ _326.60 g mol -170℃0.80g/ml661-19-8
Tricosanol C23H48O _ _ _ _340.63 g mol -13133-01-5
tetracosanollignoceryl alcoholC24H50O _ _ _ _354.65 g mol -172.9°C0.795 g/ml506-51-4
pentacosanolC25H52O _ _ _ _368.68 g mol -126040-98-2
hexacosanolceryl alcoholC26H54O _ _ _ _382.71 g mol -181°C0.789 g/mL506-52-5
heptacosanol C27H56O _ _ _ _396.73 g mol -181.5°C2004-39-9
octacosanolmontanyl alcoholC28H58O _ _ _ _410.76 g mol -183°C> 200°C0.78g/mL557-61-9
nonacosanol C29H60O _ _ _ _424.79 g mol -184°C200ºC0.78g/mL6624-76-6
triacontanolmyricyl alcohol
melissyl alcohol
C30H62O _ _ _ _438.81 g mol -187ºC0.777 g/mL593-50-0
hentriacontanol C31H64O _ _ _ _452.85 g mol -10.777 g/mL544-86-5
dotriacontanollacceryl alcoholC32H66O _ _ _ _466.87 g mol -189.4°C 6624-79-9
tritriacontanol C33H68O _ _ _ _480.89 g mol -188.6ºC 71353-61-2
tetratriacontanolgeddyl alcoholC34H70O _ _ _ _494.92 g mol -191.9°C 28484-70-0
pentatriacontanol C35H72O _ _ _ _508.95 g mol -155517-90-3
hexatriacontanol C36H74O _ _ _ _522.97 g mol -182741-64-8
heptatriacontanol C37H76O _ _ _ _536.99 g mol -1105794-58-9
octatriacontanol C38H78O _ _ _ _551.03 g mol -1141885-88-3
nonatriacontanol C39H80O _ _ _ _565.05 g mol -1
tetracontanol C40H82O _ _ _ _579.08 g mol -1164350-12-3
hentetracontanol C41H84O _ _ _ _593.11 g mol -140710-42-7
dotetracontanol C42H86O _ _ _ _607.13 g mol -11574-48-7
tritetracontanol C43H88O _ _ _ _621.16 g mol -174109-73-2
tetratetracontanol C44H90O _ _ _ _635.70 g mol -1236741-13-2
pentatetracontanol C45H92O _ _ _ _649.21 g mol -1
hexatetracontanol C46H94O _ _ _ _663.24 g mol -1172463-49-9
heptatetracontanol C47H96O _ _ _ _677.27 g mol -1195536-09-5
octatetracontanol C48H98O _ _ _ _691.29 g mol -1145315-01-1
nonatetracontanolC49H100O _ _ _ _705.32 g mol -1204375-77-9
pentacontanol C50H102O _ _ _ _719.34 g mol -140710-43-8
Methanol Ethanol And N-propanol Are Three Common Alcohols:

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